تعیین نوع ذخایر مس با سنگ میزبان آتشفشانی در ناحیه معدنی کوه‌جارو (جنوب اشتهارد) بر اساس شواهد زمین شناسی، کانه زایی و میان‌ بارهای سیال

زمین شناسی اقتصادی

مقاله 10، دوره 14، شماره 1 - شماره پیاپی 32، 1401، صفحه 67-108   

نوع مقاله: مقاله پژوهشی

شناسه دیجیتال (DOI): 10.22067/econg.2021.52100.88283

نویسندگان

ابراهیم طالع فاضل^{* 1}؛ محمد مرادی²؛ سارا نجفی راشد³

¹استادیار، گروه زمین‌ شناسی، دانشکده علوم، دانشگاه بوعلی سینا، همدان، ایران

²کارشناسی ارشد، دانشکده علوم زمین، دانشگاه اصفهان، اصفهان، ایران

³دانشجوی دکتری، گروه زمین‌شناسی، دانشکده علوم، دانشگاه بوعلی سینا، همدان، ایران

چکیده

ناحیه معدنی کوه­جارو (ذخیره احتمالی 2 میلیون تن و عیار متوسط 3 درصد مس) با راستای شرقی- غربی در دنباله آتشفشانی مردآباد- بویین ­زهرا با سن ائوسن بالایی- الیگوسن، قرار دارد. سنگ ­های آتشفشانی ائوسن بالایی با جنس ریوداسیت، تراکی ­آندزیت، آندزیت و توف تراکیتی، مهم‌ترین میزبان‌های ماده معدنی هستند. کانه‌زایی در سه مرحله شامل: 1) پیش از کانه ­زایی با حضور پیریت ­های دانه­ ریز افشان، 2) کانه ­زایی گرمابی اصلی شامل گامه ­های کانه ­زایی رگه‌ای کوارتز- کالکوپیریت± بورنیت (گامه I)، کانه‌زایی برشی بورنیت- کالکوسیت (گامه II) و کانه ­زایی افشان گالن و اسفالریت (گامه III) و 3) رگه ­های باریت و کلسیت تأخیری رخ‌داده است. طبق شواهد پتروگرافی، میان‌بارهای سیال­ در کانسارهای مس کوه جارو شامل دوفازی غنی از مایع (LV)، دوفازی غنی از گاز (VL)، دارای فاز جامد هالیت (LVS) و تک­ فازی‌های مایع (L) و گاز (V)، هستند. تغییرات دمای همگن‌شدن در این میان‌بارها بین 200 تا 350 درجه سانتی­ گراد و محتوای شوری بین 2 تا 37 درصد وزنی معادل ­نمک طعام، به‌ دست آمده است. میان‌بارهای سیال والد با چگالی بیش از 1 گرم بر سانتی‌متر مکعب و عمق تقریبی 400 متر تشکیل شدند که پس از آن، میان‌بارهایی با چگالی کمتر از 1 گرم بر سانتی‌متر مکعب و عمق کمتر از 300 متر در اثر کاهش فشار ناشی از گسلش و ورود آب­ های جوی کم دما، باعث وقوع فرایند اختلاط سیال و رخداد کانسنگ مس در سنگ ­های آتشفشانی منطقه شده ­اند. در مجموع کانسارهای مس کوه­ جارو قابل مقایسه با ذخایر مس نوع مانتو در شیلی یا مس طبقات سرخ آتشفشانی در شمال امریکا هستند.

کلیدواژه‌ها

کانه زایی مس؛ نوع مانتو؛ میان بارهای سیال؛ کوه جارو؛ اشتهارد

مراجع

Aghazadeh, M., Badrzadeh, Z., Hou, Z. and Zhou, L.M., 2015. Temporal-spatial distribution and tectonic setting of porphyry copper deposits in Iran: Constraints from zircon U-Pb and molybdenite Re-Os geochronology. Ore Geology Reviews, 70(4): 385–406. https://doi.org/10.1016/j.oregeorev.2015.03.003

Alavi, M., 1994. Tectonics of the Zagros orogenic belt of Iran: new data and interpretations. Tectonophysics, 229(2): 211–38. https://doi.org/10.1016/0040-1951(94)90030-2

Aliyari, F., Afzal, P., Harati, H. and Zengqian, H., 2019. Geology, mineralogy, ore fluid characteristics, and ⁴⁰Ar/³⁹Ar geochronology of the Kahang Cu-(Mo) porphyry deposit, Urumieh Dokhtar Magmatic Arc, Central Iran. Ore Geology Reviews, 116: 103238. https://doi.org/10.1016/j.oregeorev.2019.103238

Alizadeh, V., Momenzadeh, M. and Emami, M.H., 2013. Petrography, geochemistry, mineralogy, fluid inclusions and mineralization study of Vorezg-Qayen copper deposit. Scientific Quarterly Journal, Geosciences, 22(86): 47–58 (in Persian with English abstract). https://doi.org/10.22071/GSJ.2012.54056

Al Hakim, A.Y., Melcher, F., Prochaska, W., Bakker, R. and Rantitsch, G., 2018. Formation of epizonal gold mineralization within the Latimojong Metamorphic Complex, Sulawesi, Indonesia: Evidence from mineralogy, fluid inclusions and Raman spectroscopy. Ore Geology Reviews, 97(2): 88–108. https://doi.org/10.1016/j.oregeorev.2018.05.001

Asadi, S., Moore, F. and Zarasvandi, A., 2014. Discriminating productive and barren porphyry copper deposits in the southeastern part of the central Iranian volcano-plutonic belt, Kerman region, Iran: A review. Earth-Science Reviews, 138(5): 25–46. https://doi.org/10.1016/j.earscirev.2014.08.001

Asgharzadehasl, H., Mehrabi, B. and Tale Fazel, E., 2017. Mineralogy, occurrence of mineralization and temperature-pressure conditions of the Agh-Daragh polymetallic deposit in the Ahar-Arasbaran metallogenic area. Journal of Economic Geology, 9(1): 1–23 (in Persian with English abstract). https://doi.org/10.22067/econg.v9i1.44244

Bakker, R., 2012. Package FLUIDS. Part 4: Thermodynamic modeling and purely empirical equations for H₂O-NaCl-KCl solutions. Mineralogy and Petrology, 105(6): 1–29. https://doi.org/10.1007/s00710-012-0192-z

Bazin, D. and Hubner, H., 1969. Copper deposits in Iran. Geological survey of Iran, Tehran, Report 13, 232 pp.

Berberian, F., Muir, I.D., Pankhurst, R.J. and Berberian, M., 1982. Late Cretaceous and early Miocene Andean-type plutonic activity in northern Makran and Central Iran. Journal of Geological Society of London, 139(2): 605–14. https://doi.org/10.1144/gsjgs.139.5.0605

Bodnar, R.J., Sterner, S.M. and Hall, D.L., 1989. SALTY: a FORTRAN program to calculate compositions of fluid inclusions in the system NaCl–KCl–H₂O. Computer & Geoscience, 15(1): 19–41. https://doi.org/10.1016/0098-3004(89)90053-8

Boiron, M.C., Cathelineau, M. and Richard, A., 2010. Fluid flows and metal deposition near basement/cover unconformity: Lessons and analogies from Pb–Zn–F–Ba systems for the understanding of Proterozoic U deposits. Geofluids, 10(6): 270–292. https://doi.org/10.1111/j.1468-8123.2010.00289.x  

Boric, R., Holmgren, C., Wilson, N.S.F. and Zentilli, M., 2002. The Geology of the El Soldado Manto Type Cu (Ag) Deposit, Central Chile. In: T.M. Porter (Editors), Hydrothermal Iron Oxide Copper-Gold and Related Deposits: A Global Perspective. Porter GeoConsultancy, Adelaide, pp. 163–184.

Brown, A.C., 1971. Zoning in the White Pine copper deposit, Ontonagon County, Michigan. Economic Geology, 66(4): 543–573. https://doi.org/10.1016/0009-2541(89)90022-3

Brown, P.E., 1989. Flincor: a microcomputer program for the reduction and investigation of fluid inclusion data. American Mineralogist, 74(11–12): 1390–1393. https://pubs.geoscienceworld.org/msa/ammin/article-abstract/74/11-12/1390/42220/FLINCOR-a-microcomputer-program-for-the-reduction?redirectedFrom=fulltext

Boveiri, M., Rstad, E., Kojima, S. and Rashidnejad, N., 2013. Volcanic redbed-type copper mineralization in the Lower Cretaceous volcano-sedimentary sequence of the Keshtmahaki deposit, southern Sanandaj-Sirjan Zone, Iran. Neues Jahrbuch für Mineralogie-Abhandlungen, 27(5): 107–121. https://doi.org/10.1127/0077-7757/2013/0236

Cabral, A.R. and Beaudoin, G., 2007. Volcanic red-bed copper mineralization related to submarine basalt alteration, Mont Alexandre, Quebec Appalachians, Canada. Mineralium Deposita, 42(3): 901–912. https://doi.org/10.1007/s00126-007-0141-7

Cai, Y.T., Ni, P., Wang, G.G., Pana, J.Y., Zhu, Z.T., Chena, H. and Ding, J-Y., 2016. Fluid inclusion and H–O–S–Pb isotopic evidence for the Dongxiang Manto-type copper deposit, South China. Journal of Geochemical Exploration 171(2): 71–82. https://doi.org/10.1016/j.gexplo.2016.01.019

Cheng, X., Yang, F., Zhang, R. and Yang, C., 2019. Hydrothermal evolution and ore genesis of the Hongshi copper deposit in the East Tianshan Orogenic Belt, Xinjiang, NW China: Constraints from ore geology, fluid inclusion geochemistry and H-O-S-He-Ar isotopes. Ore Geology Reviews, 109(5): 79–100. https://doi.org/10.1016/j.oregeorev.2019.03.035

Chi, G. and Xue, Ch., 2011. An overview of hydrodynamic studies of mineralization. Geosciences Frontiers, 2(3): 423–438. https://doi.org/10.1016/j.gsf.2011.05.001

Corbett, G. and Leach, T.M., 1998. Southwest Pacific Rim gold-copper systems: Structure, alteration, and mineralization. Society of Economic Geologists, United State of American, 237 pp.

Cox, K.G., Bell, J.D. and Pankhurts, R.J., 1979. The interpretation of igneous rocks. Springer, London, 450 pp.

Driesner, T. and Heinrich, C.A., 2007. The system H₂O–NaCl. Part I: Correlation formulae for phase relations in temperature–pressure–composition space from 0 to 1000 °C, 0 to 5000 bar, and 0 to 1 XNaCl. Geochimica et Cosmochimica Acta, 71(5): 4880–4901. https://doi.org/10.1016/j.gca.2006.01.033

Hall, D.L., Sterner, S.M. and Bodnar, R.J., 1988. Freezing point depression of NaCl-KCl-H₂O solutions. Economic Geology, 83(3): 197–202. https://doi.org/10.2113/GSECONGEO.83.1.197

Heinrich, C.A. and Candela. P.A., 2014. Fluids and Ore Formation in the Earth’s Crust. Treatise on Geochemistry, 2(1): 1–28. https://doi.org/10.1016/B978-0-08-095975-7.01101-3

Henley, R.W., King, P.L., Wykes, J.L., Renggli, C.J., Brink, F.J., Clark, D.A. and Troitzsch, U., 2015. Porphyry copper deposit formation by sub-volcanic sulphur dioxide flux and chemisorption. Nature Geoscience, 8(3): 210–215. https://doi.org/10.1038/ngeo2367

Hosseini, M., 1996. Economic geology of the southeast Eshtehard. M.Sc. Thesis, Shahid Beheshti University, Tehran, Iran, 478 pp.

Jamali, H., Dilek, Y., Daliran, F., Yaghubpur, A.M. and Mehrabi, B., 2009. Metallogeny and tectonic evolution of the Cenozoic Ahar-Arasbaran volcanic belt, northern Iran. International Geology Review, 52(7): 608–630. https://doi.org/10.1080/00206810903416323

Javidi Moghaddam, M., Hassan Karimpour, M., Malekzadeh Shafaroudi, A., Francisco Santos, J. and Helena Mendes, M., 2019. Geochemistry, Sr-Nd isotopes and zircon U-Pb geochronology of intrusive rocks: Constraint on the genesis of the Cheshmeh Khuri Cu mineralization and its link with granitoids in the Lut Block, Eastern Iran. Journal of Geochemical Exploration, 202(3): 59–76. https://doi.org/10.1016/j.gexplo.2019.04.001

Kansaran Consultant Engineering Co., 1994. Geology and mineral deposits of the southeast Eshtehard (Jarou). Ministry of industrial and mines, 300 pp.

Khoei, N., Ghorbani, M. and Tajbakhsh, P., 1999. Copper deposits in Iran. Geological Survey of Iran, Tehran, 421 pp.

Kirkham, R.V., 1984. Volcanic red bed copper. Geological Survey of Canada, Canada, Report 36, 37 pp.

Kirkham, R.V., 1996. Volcanic redbed copper. In: O.R. Eckstrand, W.D. Sinclair and R.I. Thorpe (Editors), Geology of Canadian mineral deposit types. Geological Survey of Canada, Canada, pp. 241–252.

Klohn, E., Holmgren, C., Ruge, H., 1990. El Soldado, a strata-bound copper deposit associated with alkaline volcanism in the Central Chilean Coastal Range. In: L. Fontboté, G.C. Amstutz, M. Cardozo, E. Cedillo and J. Frutos (Editors), Strata-bound ore deposits in the Andes. Springer, Berlin, pp. 435–448.

Kojima, S., Trista-Aguilera, D. and Hayashi, K., 2008. Genetic Aspects of the Manto-type Copper Deposits Based on Geochemical Studies of North Chilean Deposits. Resource Geology, 59(3): 87–98. https://doi.org/10.1111/j.1751-3928.2008.00081.x

Kouhestani, H., Mokhtari, M.A.A., Chang, Z. and Johnson, C.A., 2018. Intermediate sulfidation type base metal mineralization at Aliabad-Khanchy, Tarom-Hashtjin metallogenic belt, NW Iran. Ore Geology Reviews, 93(5): 1–18. https://doi.org/10.1016/j.oregeorev.2017.12.012

Kouhestani, H., Mokhtari, M.A.A., Qin, K.Z. and Zhao, J.X., 2019. Fluid inclusion and stable isotope constraints on ore genesis of the Zajkan epithermal base metal deposit, Tarom-Hashtjin metallogenic belt, NW Iran. Ore Geology Reviews, 109(3): 564–584. https://doi.org/10.1016/j.oregeorev.2019.05.014

Larson, P.B., Maher, K., Ramos, F.C., Chang, Z., Gaspar, M. and Meinert, L.D., 2003. Copper isotope ratios in magmatic and hydrothermal ore-forming environments. Chemical Geology, 201(3): 337– 350. https://doi.org/10.1016/j.chemgeo.2003.08.006

Lefebure, D.V. and Church, B.N., 1996. Volcanic Redbed Cu, in Selected British Columbia Mineral Deposit Profiles. In: D.V. Lefebure, and T. Hõy (Editors), Metallic Deposits. Ministry of Employment and Investment, British Columbia, pp. 5–7.

Liebscher, A. and Heinrich, C.A., 2007. Fluid-fluid interactions in the Earth's Lithosphere. Reviews in Mineralogy and Geochemistry, 65(1): 1–13. https://doi.org/10.2138/rmg.2007.65.1

Mahdizade Tehrani, S., 1995. Geological map of Karaj, Scale 1:100,000. Geological Survey of Iran.

Mahvashi, M. and Malekzadeh Shafaroudi, A., 2016. Cheshme Gaz (Nasim) copper deposit (NW Bardeskan): Mineralogy, alteration, geochemistry and model. Iranian Journal of Crystallography and Mineralogy, 23(3): 419–434.

Malekzadeh Shafaroudi, A. and Karimpour, M.H., 2015. Mineralogic, fluid inclusion, and sulfur isotope evidence for the genesis of Sechangi lead-zinc (copper) deposit, Eastern Iran. Journal of African Earth Sciences, 107(1): 1–14. https://doi.org/10.1016/j.jafrearsci.2015.03.015

Maghfouri, S., Hosseinzadeh, M.R., Moayyed, M., Movahednia, M. and Choulet, F., 2016. Geology, mineralization and sulfur isotopes geochemistry of the Mari Cu (Ag) Manto-type deposit, northern Zanjan, Iran. Ore Geology Reviews, 81(5): 10–22. https://doi.org/10.1016/j.oregeorev.2016.10.025

Mehrabi, B., Ghasemi Siani, M., Goldfarb, R., Azizi, H., Ganerod, M. and Marsh, E.E., 2016. Mineral assemblages, fluid evolution and genesis of polymetallic epithermal veins, Gulojeh district, NW Iran. Ore Geology Reviews, 78(4): 41–57. https://doi.org/10.1016/j.oregeorev.2016.03.016

Mehrabi, B., Chaghaneh, N. and Tale Fazel., 2014. The intermediate-sulfidation epithermal of the IV prospect of Golojeh deposit (N. Zanjan): Mineralography, alteration and ore-forming fluid geochemistry evidences. Journal of Economic Geology, 6(1): 1–22. (in Persian with English abstract) https://doi.org/10.22067/econg.v6i1.38302

Mohammadiasl, Z., Saidi A., Arian, M., Solgi A. and Farhadinejad, T., 2019. Veshnoveh Cu mine located in Kahak South-east geodynamic place (South of Qom). Scientific Quarterly Journal, Geosciences, 29(114): 175–184. (in Persian with English abstract) http://dx.doi.org/10.22071/gsj.2018.95329.1226

Nogole-Sadat, M.A.A. and Hushmandzadeh, A., 1984. Geological map of Saveh, Scale 1:250,000. Geological Survey of Iran.

Oliveros, V., Féraud, G., Aguirre, L., Ramírez, L., Fornari, M., Palacios, C. and Parada, M., 2008. Detailed ⁴⁰Ar/³⁹Ar dating of geologic events associated with the Mantos Blancos copper deposit, northern Chile. Mineralium Deposita, 43(2): 281–293. http://dx.doi.org/10.1007/s00126-007-0146-2

Omrani, J., Agard, P., Whitechurch, H., Benoit, M., Prouteau, G. and Jolivet, L., 2008. Arc-magmatism and subduction history beneath the Zagros Mountains, Iran: A new report of adakites and geodynamic consequences. Lithos, 106(3): 380–398. https://doi.org/10.1016/j.lithos.2008.09.008

Pollard, P.J., 2006. An intrusion-related origin for Cu–Au mineralization in iron oxide–copper–gold (IOCG) provinces. Mineralium Deposita, 41(2): 179–187. https://doi.org/10.1007/s00126-006-0054-x

Rabiee, A., Rossetti, F., Tecce, F., Asahara, Y., Azizi, H., Glodny, J., Lucci, F., Nozaem, R., Opitz, J. and Selby, D., 2019. Multiphase magma intrusion, ore-enhancement and hydrothermal carbonatisation in the Siah-Kamar porphyry Mo deposit, Urumieh-Dokhtar magmatic zone, NW Iran. Ore Geology Reviews, 110(3): 102930. https://doi.org/10.1016/j.oregeorev.2019.05.016

Rahgozar, Sh., 1999. Genesis of the Gomosh Dash polymetallic mine at Kuh-e Jarou area. M.Sc. Thesis, Shahid Beheshti University, Tehran, Iran, 238 pp.

Rajabpour, S., Behzadi, M., Jiang, S-Y., Rasa, I., Lehmann, B. and Ma, Y., 2017. Sulfide chemistry and sulfur isotope characteristics of the Cenozoic volcanic-hosted Kuh-Pang copper deposit, Saveh county, northwestern Central Iran. Ore Geology Reviews, 86(7): 563–583. https://doi.org/10.1016/j.oregeorev.2017.03.001

Ramirez, L.E., Palacios, C., Townley, B., Parada, M.A., Sial, A.N., Fernandez- Turiel, J.L., Gimeno, D., Garcia-Valles, M. and Lehmann, B., 2006. The Mantos Blancos copper deposit: An upper Jurassic breccia-style hydrothermal system in the coastal range of northern Chile. Mineralium Deposita, 41(3): 246–258. https://doi.org/10.1007/s00126-006-0055-9

Rezaeihamid, R., Tale Fazel, E. and Niroomand, Sh., 2019. Minralization and genesis of the Baharieh Cu deposit (NE Kashmar) based on mineralography, geochemistry and fluid inclusion evidences. Scientific Quarterly Journal, Geosciences, 28(112): 43–58. (in Persian with English abstract) https://doi.org/10.22071/GSJ.2018.104610.1306

Rosúa, J., Boyce, A., Morales-Ruano, S., Morata, D., Roberts, S., Munizaga, F. and Rodríguez, V., 2014. Extremely negative and inhomogeneous sulfur isotope signatures in Cretaceous Chilean manto-type Cu–(Ag) deposits, Coastal Range of central Chile. Ore Geology Reviews, 56(4): 13–24. https://doi.org/10.1016/j.oregeorev.2013.06.013

Rosemeyer, T., 2011. News from the Keweenaw, Recent Mineral Finds in Michigan’s Copper Country. Rocks and Minerals, 73(3): 182-195. https://doi.org/10.1080/00357529809603034

Ruiz, C., Aguilar, A., Egert, E., Espinoza, W., Peebles, F., Quezada, R. and Serrano, M., 1971. Strata-bound copper sulphide deposits of Chile. Society of Mining Geology of Japan, 39(2): 252–260. https://doi.org/10.1007/978-3-642-88282-1

Salehi, L., Rasa, I., Alirezaei, S. and Kazemi Mehrnia, A. 2016. The Madan Bozorg, volcanic-hosted copper deposit, East Shahroud; a example of Manto type copper deposits in Iran. Scientific Quarterly Journal, Geosiences, 25(98): 93–104. (in Persian with English abstract) https://doi.org/10.22071/GSJ.2016.41166

Samani, B., 2001. Metallogeny of Manto-type Deposits in Iran. 6th Symposium of Iranian Geosciences, Shahid Bahonar University of Kerman, Kerman, Iran.

Samani, B., 1998. Distribution, setting and metallogenesis of copper deposits in Iran. In: T.M. Porter (Editor), Porphyry and Hydrothermal Copper & Gold Deposits: A Global Perspective. PGC Publishing, Adelaide, pp. 151–174.

Sato, T., 1984. Manto type copper deposits in Chile: A review. Bulltein of Geological Survey of Japan, 35(3): 565–582. https://doi.org/10.1111/j.1751-3928.2008.00081.x

Şengör, A.M.C., 1987. Tectonics of the Tethysides: orogenic collage development in a collisional setting. Earth and Planetary Science Letters, 15(3): 213–244. https://doi.org/10.1146/annurev.ea.15.050187.001241

Shafiei, B., Haschke, M. and Shahabpour, J., 2009. Recycling of orogenic arc crust triggers porphyry Cu mineralization in Kerman Cenozoic arc rocks, southeastern Iran. Mineralium Deposita, 44(5): 265–283. https://doi.org/10.1007/s00126-008-0216-0

Shepherd, T.J., Rankin, A.H. and Alderton, D.H., 1985. A practical guide to fluid inclusion studies. Glasgow Blackie and Sons, Glasgow, 239 pp.

Tale Fazel, E., Mehrabi, B. and Shabani, Tabbakh, A.A., 2015. Kuh-e Dom Fe–Cu–Au prospect, Anarak Metallogenic Complex, Central Iran: a geological, mineralogical and fluid inclusion study. Mineralogy and Petrology, 109(5): 115–141.  https://doi.org/10.1007/s00710-014-0354-2

Tale Fazel, E., Mehrabi, B. and Ghasemi Siani, M., 2019. Epithermal systems of the Torud-Chah Shirin district, northern Iran: Ore fluid evolution and geodynamic setting. Ore Geology Reviews, 109(3): 253–275. https://doi.org/10.1016/j.oregeorev.2019.04.014

Technoexport, 1981. Detail geology prospecting in the Anarak Area Central Iran. Geological Survey of Iran, Tehran, Report 9, 120 pp.

Tooti, F., 1991. Petrology of volcanic rocks of the Kuh-e Jarou area (southeast Eshtehard). M.Sc. Thesis, University of Tehran, Tehran, Iran, 131 pp.

Whitney, D.L. and Evans, B.W., 2010. Abbreviations for names of rock-forming minerals. American Mineralogist, 95(3): 185–187. https://doi.org/10.2138/am.2010.3371

Wilkinson, J.J., 2001. Fluid inclusions in hydrothermal ore deposits. Lithos, 55(3): 229–272. https://doi.org/10.1016/S0024-4937(00)00047-5

Wilson, N.S.F., 2000. Organic petrology, chemical composition, and reflectance of pyrobitumen from the El Soldado Cu deposit, Chile. International Journal of Coal Geology, 43(3): 53–82. https://doi.org/10.1016/S0166-5162(99)00054-3

Wilson, N.S.F. and Zentilli, M., 2006. Association of pyrobitumen with copper mineralization from the Uchumi and Talcuna districts, central Chile. International Journal of Coal Geology, 65(4): 158–169. https://doi.org/10.1016/j.coal.2005.04.012

Wilson, N.S.F., Zentilli, M. and Spiro, B., 2003. A sulfur, carbon, oxygen, and strontium isotope study of the volcanic-hosted El Soldado Manto-Type copper deposit, Chile: the essential role of bacteria and petroleum. Economic Geology, 98(1): 163–174. https://doi.org/10.2113/gsecongeo.98.1.163

Zarasvandi, A., Rezaei, M., Raith, J., Lentz, D.R., Azimzadeh, A.M. and Pourkaseb, H., 2015. Geochemistry and fluid characteristics of the Dalli porphyry Cu-Au deposit, Central Iran. Journal of Asian Earth Sciences, 111(2): 175-191.  https://doi.org/10.1016/j.jseaes.2015.07.029

Zar-Azin Gostar Consultant Engineering Co., 2009. General exploration report of the copper deposits at Jarou-Eshtehard area. Iranian Mines and Mineral Industries Development and Renovation Organization, Tehran, Report 1, 222 pp.

Zhang, Y.-G. and Frantz, J.D., 1987. Determination of the homogenization temperatures and densities of supercritical fluids in the system NaCl-KCl-CaCl₂-H₂O using synthetic fluid inclusions. Chemical Geology, 64(4): 335–350. https://doi.org/10.1016/0009-2541(87)90012-X

Zhong, R., Li, W., Chen, Y., Yue, D. and Yang, Y., 2013. P-T-X conditions, origin, and evolution of Cu-bearing fluids of the shear zone-hosted Huogeqi Cu–(Pb–Zn–Fe) deposit, northern China. Ore Geology Reviews, 50(2): 83–97. https://doi.org/10.1016/j.oregeorev.2012.10.003