تأثیر ولتاژ و زمان رسوب‌نشانی الکتریکی بر خواص الکتروکرومیکی پوشش‌های WO3

مهندسی متالورژی و مواد

مقاله 1، دوره 36، شماره 1 - شماره پیاپی 37، فروردین 1404، صفحه 1-14   

نوع مقاله: علمی و پژوهشی

شناسه دیجیتال (DOI): 10.22067/jmme.2024.85499.1129

نویسندگان

پریسا کاظمی زاده؛ مصطفی میرجلیلی^* ؛ قاسم براتی دربند

گروه مهندسی مواد و متالورژی، دانشکده مهندسی، دانشگاه فردوسی مشهد، ایران.

چکیده

مواد الکتروکرومیک وقتی در میدان الکتریکی قرار می‌گیرند، تغییر رنگ می‌دهند و از مهم‌ترین کاربرد‌های این مواد، می‌توان به پنجره‌های هوشمند اشاره کرد. این پنجره‌ها نقش مهمی در صرفه جویی مصرف انرژی و هم‌چنین کنترل شرایط نوری و دمایی اتاق دارند. اکسید تنگستن به عنوان یک ماده الکتروکرومیک، به دلیل بازده رنگی بالا توجه زیادی از پژوهشگران را به خود جلب کرده است. در مطالعه حاضر، به تاثیر ولتاژ و زمان برخواص الکتروکرومیک جهت رسیدن به شرایط بهینه رسوب‌نشانی اکسید‌‎‌ تنگستن به روش رسوب‌نشانی الکتریکی پرداختیم. آزمایش‌هایی که بر اساس ویژگی‌های نوری، ریزساختاری و چرخه ولتامتری انجام شد، نشان داد که ولتاژ کاتدی450- میلی‌ولت ( نسبت به الکترود مرجع Ag/AgCl ) و زمان رسوب‌نشانی 3 دقیقه باعث بهبود ویژگی‌های الکتروکرومیکی لایه‌های اکسید تنگستن در الکترولیت سولفوریک اسید یک مولار شده است. میزان بازده رنگی برای این لایه cm2/C 12.16به دست آمد و پایداری مناسبی تا 100 چرخه از خود نشان داده است.

کلیدواژه‌ها

الکتروکرومیک؛ رسوب‌نشانی الکتریکی؛ اکسید تنگستن؛ شیشه ITO

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