Evaluation of Cr in ophiolite and groundwater and its potential to contaminate the environment in SE of Birjand

زمین شناسی اقتصادی

Article 6, Volume 4, Issue 2 - Serial Number 7, December 2012, Pages 335-350   

Document Type: Research Article

DOI: 10.22067/econg.v4i2.16500

Authors

Zahra Khaledi^* ; Hossein Mohammadzadeh

Ferdowsi University of Mashhad

Abstract

The presence of Cr(VI) in groundwater resources is governed by pH and Eh of water and its compounds are generally soluble and have more toxicicity and mobility in oxidizing environments. In this article, the Cr concentration in ophiolite units, in sediments, and in groundwater resources, and also its potential to contaminate the environment have been investigated in southeast of Birjand. During sampling, 17 water samples (2 rain water samples and 15 groundwater samples), and 8 sediment samples were collected. The concentrations of cations (major cations and Cr) and anions in water samples were measured at Ottawa University, Canada using IC and ICP-AES methods, respectively. Cr concentrations of sediments were measured using XRF, and concentrations of Cr in collected Selective Sequential Extraction (SSE) fractions were measured using Atomic Absorption (AA) at Ferdowsi University of Mashhad, Iran. The average Cr concentrations in sediments and water resources are 627 and 0.026 ppm, respectively. According to the pH of sediments and Eh-pH of water samples, the Cr in water resources is as Cr(VI). Furthermore, the results of SSE show that the majority of Cr was found with residual matter, attached to the iron and manganese oxides, bound to carbonates, organic matter, and the soluble fractions, respectively. The hydrogeochemical properties of water resources show that the average values of EC, TDS and pH are 509 mg/l, 1045 µs/cm and 8.1, respectively, and the concentrations of Cl-, Na+, Mg2+ and SO42- ions are higher than the levels of WHO and Iran National Standard (1053). According to the WQI classification, while 20 percent of the water resources have excellent quality, 53 percent show good quality and 20 percent of water resources are poor in quality.

Keywords

Ophiolite; Cr concentration; Sediment; SSE; mobility factor; Groundwater; WQI; Birjand

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