تغییر در قابلیت استفاده و اجزاء مس در ریزوسفر آفتابگردان در خاک آلوده تیمارشده با کلات کننده ها

آب و خاک

مقاله 2، دوره 31، شماره 2 - شماره پیاپی 52، تیر 1396، صفحه 509-521   

نوع مقاله: مقالات پژوهشی

شناسه دیجیتال (DOI): 10.22067/jsw.v31i2.53346

نویسندگان

محمد رحمانیان^{* 1}؛ علیرضا حسین پور²؛ ابراهیم ادهمی¹؛ حمیدرضا متقیان²

¹دانشگاه یاسوج

²دانشگاه شهرکرد

چکیده

ویژگی‌های زیستی و شیمیایی محیط ریزوسفر از جمله فراهمی و اجزاء شیمیایی فلزات در آن با توده خاک متفاوت است. این پژوهش به منظور بررسی تغییر در قابلیت‌استفاده و اجزاء مس در ریزوسفر آفتابگردان (Helianthus annuus L.) در یک خاک شنی آلوده به مس تیمار‌شده با کلات-کننده‌ها (EDTA، اسید سیتریک و عصاره کود مرغی) در شرایط گلخانه‌ای انجام شد.EDTA و اسید سیتریک در سطوح غلظتی صفر، 5/0 و 1 ‌میلی-مول بر کیلوگرم خاک و عصاره کود مرغی در سطوح غلظتی صفر، 5/0 و 1 گرم بر کیلوگرم خاک استفاده شدند. تعداد سه بذر آفتابگردان در هر ریزوباکس کاشته شد. بعد از 10 هفته گیاهان برداشت شدند و خاک‌های ریزوسفری و توده جدا شدند. مس قابل‌استفاده با استفاده از 7 روش عصاره‌گیری شیمیایی و جزءبندی مس در خاک‌های ریزوسفری و توده اندازه‌گیری شد. ویژگی‌های خاک ریزوسفری با خاک توده متفاوت بود. مقدار مس عصاره‌گیری شده به روش‌های مختلف در خاک‌های ریزوسفری کمتر از خاک‌های توده بود. دامنه تغییرات مس عصاره‌گیری شده با عصاره‌گیرها از 023/0 تا 83/1 میلی‌گرم بر کیلوگرم بود. در خاک‌های ریزوسفری و توده تیمارشده با کلات‌کننده‌ها، بیشترین مقادیر مس به ترتیب در اجزاء باقیمانده، پیوند‌شده با ماده آلی، پیوند‌شده با اکسیدهای آهن و منگنز، پیوند‌شده با کربنات‌ها و تبادلی بود. میانگین اجزاء مس پیوند‌شده با کربنات‌ها، پیوند‌شده با اکسیدهای آهن و منگنز و جزء باقیمانده در شرایط ریزوسفری بیشتر از توده خاک بود. میانگین جزء پیوند‌شده با ماده آلی در شرایط ریزوسفری کمتر از توده خاک بود. دامنه تغییرات اجزاء مس از 81/2 تا 95/12 میلی‌گرم بر کیلوگرم بود.

کلیدواژه‌ها

جزءبندی؛ توده خاک؛ EDTA؛ اسید سیتریک؛ عصاره کود مرغی

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