ارزیابی مورفولوژی و مکانیزم‌‌های شکل‌گیری نانوذرات اکسید روی و اکسید مس ساخته شده به روش هم‌رسوبی

مهندسی متالورژی و مواد

مقاله 7، دوره 33، شماره 1 - شماره پیاپی 25، اسفند 1400، صفحه 97-106  

نوع مقاله: علمی و پژوهشی

شناسه دیجیتال (DOI): 10.22067/jmme.2021.72313.1027

نویسندگان

نرگس جوهری ؛ فائزه زهری؛ فاطمه رفعتی

گروه مهندسی مواد، دانشکدۀ فنی مهندسی گلپایگان، دانشگاه صنعتی اصفهان، گلپایگان.

چکیده

یکی از عوامل مهم در تعیین خواص متنوع نانوذرات، مانند خواص مکانیکی، فیزیکی، نوری، مغناطیسی، الکتریکی و بیولوژیکی، مورفولوژی آن‌‌هاست. در این پژوهش، نانو ذرات اکسید روی (ZnO) و اکسید مس (CuO) به روش هم‌رسوبی با پروتکل‌های یکسان ساخته شدند. نیترات روی و سولفات مس به ترتیب به‌عنوان پیش سازه‌های اکسید روی و اکسید مس انتخاب شدند. ساختار بلوری و فازهای شکل گرفته و مورفولوژی نانوذرات ایجاد شده به ترتیب با پراش پرتو ایکس (XRD) و میکروسکوپ الکترونی روبشی (SEM) مورد ارزیابی قرار گرفتند. بررسی ساختار بلوری، فازهای شکل یافته و مورفولوژی هر دو نانو ذره نشان داد که اکسید روی و اکسید مس بدون هیچ گونه ناخالصی و با مورفورلوژی‌های متفاوت ساخته شدند. نانو ذرات اکسید روی و اکسید مس بدست آمده به ترتیب ساختارهای کروی-الماسی شکل و سلسله مراتبی گل مانند داشتند که این مورفولوژی‌‌های متفاوت ناشی از ساختارهای بلورین متفاوت و برهمکنش‌های الکترواستاتیکی مختلف بین آنیون‌ها و سطوح قطبی آن‌ها مربوط می‌‌شود که در نهایت منجر به ساختارهای متفاوت آن‌ها می‌شود.

کلیدواژه‌ها

نانوذرات اکسید روی؛ نانوذرات اکسید مس؛ مورفولوژی؛ مکانیزم

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